Alloys 309 and Alloys 309S are austenitic chromium-nickel stainless steels that are often used for higher temperature applications. Due to their high chromium and nickel content, Alloys 309 and 309S are highly corrosion resistant, have outstanding resistance to oxidation, and excellent heat resistance while providing good strength at room and elevated temperatures. The only significant difference between 309 and 309S is the carbon content. Alloy 309S has a much less carbon composition which minimizes carbide precipitation and improves weldability.

Alloy 309 (UNS S30900) is an austenitic stainless steel developed for use in high temperature corrosion resistance applications. The alloy resists oxidation up to 1900°F (1038°C) under non-cyclic conditions. Frequent thermal cycling reduces oxidation resistance to approximately 1850°F (1010°C).

Because of its high chromium and low nickel content, Alloy 309 can be utilized in sulfur containing atmospheres up to 1832°F (1000°C). The alloy is not recommended for use in highly carburizing atmospheres since it exhibits only moderate resistance to carbon absorption. Alloy 309 can be utilized in slightly oxidizing, nitriding, cementing and thermal cycling applications, albeit, the maximum service temperature must be reduced.

When heated between 1202 – 1742°F (650 – 950°C) the alloy is subject to sigma phase precipitation. A solution annealing treatment at 2012 – 2102°F (1100 – 1150°C) will restore a degree of toughness.

309S (UNS S30908) is the low carbon version of the alloy. It is utilized for ease of fabrication. 309H (UNS S30909) is a high carbon modification developed for enhanced creep resistance. It most instances the grain size and carbon content of the plate can meet both the 309S and 309H requirements.